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dc.contributor.advisorPeyghambarian, Nasser N.en_US
dc.contributor.advisorKippelen, Bernarden_US
dc.contributor.authorHaddock, Joshua Naaman
dc.creatorHaddock, Joshua Naamanen_US
dc.date.accessioned2011-12-06T14:15:15Z
dc.date.available2011-12-06T14:15:15Z
dc.date.issued2005en_US
dc.identifier.urihttp://hdl.handle.net/10150/195956
dc.description.abstractDiffractive optical elements in which discrete phase levels are used to approximate a continuous blaze profile offer the advantage over conventional refractive optics in that they are essentially planar structures and thus consume very little space. Furthermore, it has been shown that switchable diffractive elements can be fabricated using electro-optic materials such as inorganic electro-optic crystals and liquid crystals. In this work, liquid crystal diffractive lenses are investigated for their possible use as switchable spectacle lenses, an alternative to current bifocal and progressive lens technologies. In these lenses, discrete, rotationally symmetric electrodes are used to generate the stepped phase levels of a diffractive lens in a 5 micrometer layer of nematic liquid crystal. Near theoretical diffraction efficiencies are reported for both 2 and 4 phase level lenses and it is shown that the inter-electrode gap is a critical design parameter for achieving these values. For the 4 level lenses the near theoretical values are achieved by implementing a novel, multi-level electrode structure that eliminates the inter-electrode gap while maintaining electrical isolation between adjacent electrodes. Additionally, the results of a study aimed at reducing the operating voltages of nematic liquid crystal are also included. In this study, colorless molecular dopants with high dipole moments are added to commercial nematic liquid crystal mixtures for the purpose of increasing dielectric anisotropy, upon which the threshold voltage is inversely dependent. While a reduction in threshold voltage is observed it is determined that a reduction in order parameter is the cause. Quantum-chemical analysis of the dopant molecules indicate that the structures are too rigid for introduction into a liquid crystal host and a new, less rigid structure is proposed.
dc.language.isoenen_US
dc.publisherThe University of Arizona.en_US
dc.rightsCopyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author.en_US
dc.titleLiquid Crystal Based Electro-Optic Diffractive Spectacle Lenses and Low Operating Voltage Nematic Liquid Crystalsen_US
dc.typetexten_US
dc.typeElectronic Dissertationen_US
dc.contributor.chairPeyghambarian, Nasser N.en_US
dc.contributor.chairKippelen, Bernarden_US
dc.identifier.oclc137354919en_US
thesis.degree.grantorUniversity of Arizonaen_US
thesis.degree.leveldoctoralen_US
dc.contributor.committeememberWright, Ewanen_US
dc.contributor.committeememberArmstrong, Neal R.en_US
dc.identifier.proquest1304en_US
thesis.degree.disciplineOptical Sciencesen_US
thesis.degree.disciplineGraduate Collegeen_US
thesis.degree.namePh.D.en_US
refterms.dateFOA2018-06-17T09:40:25Z
html.description.abstractDiffractive optical elements in which discrete phase levels are used to approximate a continuous blaze profile offer the advantage over conventional refractive optics in that they are essentially planar structures and thus consume very little space. Furthermore, it has been shown that switchable diffractive elements can be fabricated using electro-optic materials such as inorganic electro-optic crystals and liquid crystals. In this work, liquid crystal diffractive lenses are investigated for their possible use as switchable spectacle lenses, an alternative to current bifocal and progressive lens technologies. In these lenses, discrete, rotationally symmetric electrodes are used to generate the stepped phase levels of a diffractive lens in a 5 micrometer layer of nematic liquid crystal. Near theoretical diffraction efficiencies are reported for both 2 and 4 phase level lenses and it is shown that the inter-electrode gap is a critical design parameter for achieving these values. For the 4 level lenses the near theoretical values are achieved by implementing a novel, multi-level electrode structure that eliminates the inter-electrode gap while maintaining electrical isolation between adjacent electrodes. Additionally, the results of a study aimed at reducing the operating voltages of nematic liquid crystal are also included. In this study, colorless molecular dopants with high dipole moments are added to commercial nematic liquid crystal mixtures for the purpose of increasing dielectric anisotropy, upon which the threshold voltage is inversely dependent. While a reduction in threshold voltage is observed it is determined that a reduction in order parameter is the cause. Quantum-chemical analysis of the dopant molecules indicate that the structures are too rigid for introduction into a liquid crystal host and a new, less rigid structure is proposed.


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