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    Radius Effect of the Alkaline Earths on the Rate of Inversion of Aragonite to Calcite

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    Master's Thesis Full PDF
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    Author
    Bennett, Catheryn MacDonald
    Issue Date
    1972
    Keywords
    alkaline earth metals
    aragonite
    calcite
    carbonates
    metals
    minerals
    phase equilibria
    solid solution
    Aragonite
    Calcite
    Committee Chair
    Schreiber, Joseph F. Jr.
    
    Metadata
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    Publisher
    The University of Arizona.
    Rights
    Copyright © is held by the author. Digital access to this material is made possible by the Antevs Library, Department of Geosciences, and the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author or the department.
    Collection Information
    This item is part of the Geosciences Theses collection. It was digitized from a physical copy provided by the Antevs Library, Department of Geosciences, University of Arizona. For more information about items in this collection, please email the Antevs Library, antevs@geo.arizona.edu.
    Abstract
    The effect of magnesium, strontium, and other alkaline earths on the formation and persistence of metastable carbonates in the natural environment was investigated to determine the nature of the controlling mechanism. Barium and beryllium were studied to evaluate the effect of ionic radius; magnesium and strontium, in order to determine if the results correlate with the usual order of stability for complexes and adsorbed species. Known weights of aragonite were placed in contact with solutions of beryllium, magnesium, calcium, strontium, and barium. Samples were covered and periodically both pH and percent composition of aragonite determined; supernatant liquids and precipitates were analyzed for cation concentrations by atomic absorption spectroscopy and titrimetric methods. Results indicated that the order of effectiveness of alkaline earth metals in inhibiting recrystallization is : Be > Mg > Sr > Ba. This is the expected order of effectiveness for both surface and solution effects. A solution effect (i.e., sequestration of bicarbonate ions) is strongly suggested by the chemical behavior of each cation.
    Type
    text
    Thesis-Reproduction (electronic)
    Degree Name
    M.S.
    Degree Level
    masters
    Degree Program
    Graduate College
    Geosciences
    Degree Grantor
    University of Arizona
    Collections
    Geosciences Theses

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