Laser spectroscopy of strontium-sulfide and alkaline earth monoborohydrides
| dc.contributor.advisor | Bernath, Peter F. | en_US |
| dc.contributor.author | Pianalto, Frederick Scott, 1961- | |
| dc.creator | Pianalto, Frederick Scott, 1961- | en_US |
| dc.date.accessioned | 2013-03-28T10:15:35Z | |
| dc.date.available | 2013-03-28T10:15:35Z | |
| dc.date.issued | 1988 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10150/276739 | |
| dc.description.abstract | Three gas phase alkaline earth molecules were analyzed using dye laser spectroscopy. The A¹Σ⁺ - X¹Σ⁺ transition of gas phase SrS was studied with high resolution techniques. The 0-0, 0-1, 1-1, 2-1, 3-0, 3-2, 4-1, 5-1, and 5-2 bands were rotationally analyzed and spectroscopic constants were determined. The A¹Σ⁺ state was extensively perturbed. Ground state (X¹Σ⁺) constants derived from the analysis of the nine vibrational levels include: ωₑ = 388.2643 cm⁻¹, Bₑ = 0.1208034(33) cm⁻¹, and rₑ = 2.439687(14) Å. Excited state (A¹Σ⁺) constants determined include: Tₑ = 13932.7068(10) cm⁻¹, ωₑ = 339.1454(20) cm⁻¹, Bₑ = 0.1139895(38) cm⁻¹, and rₑ = 2.511601(17) Å. The spectra of calcium and strontium borohydrides were observed using low resolution laser spectroscopy. The spectra were assigned to the òA₁ - Ẋ²A₁ and Ḃ²E - Ẋ²A₁ transitions of CaBH₄ and SrBH₄. The vibrational frequencies of the metal-ligand stretch determined for CaBH₄ were 457 cm⁻¹ (Ẋ²A₁), 473 cm⁻¹ (Ā²A₁), and 465 cm⁻¹ (Ḃ²E). The corresponding SrBH4 frequencies were 399 cm⁻¹, 420 cm⁻¹, and 421 cm⁻¹. | |
| dc.language.iso | en_US | en_US |
| dc.publisher | The University of Arizona. | en_US |
| dc.rights | Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author. | en_US |
| dc.subject | Strontium compounds -- Spectra. | en_US |
| dc.subject | Hydrides -- Spectra. | en_US |
| dc.subject | Gases -- Spectra. | en_US |
| dc.title | Laser spectroscopy of strontium-sulfide and alkaline earth monoborohydrides | en_US |
| dc.type | text | en_US |
| dc.type | Thesis-Reproduction (electronic) | en_US |
| dc.identifier.oclc | 21105889 | en_US |
| thesis.degree.grantor | University of Arizona | en_US |
| thesis.degree.level | masters | en_US |
| dc.identifier.proquest | 1333612 | en_US |
| thesis.degree.discipline | Graduate College | en_US |
| thesis.degree.discipline | Chemistry | en_US |
| thesis.degree.name | M.S. | en_US |
| dc.identifier.bibrecord | .b17161423 | en_US |
| refterms.dateFOA | 2018-08-17T07:47:46Z | |
| html.description.abstract | Three gas phase alkaline earth molecules were analyzed using dye laser spectroscopy. The A¹Σ⁺ - X¹Σ⁺ transition of gas phase SrS was studied with high resolution techniques. The 0-0, 0-1, 1-1, 2-1, 3-0, 3-2, 4-1, 5-1, and 5-2 bands were rotationally analyzed and spectroscopic constants were determined. The A¹Σ⁺ state was extensively perturbed. Ground state (X¹Σ⁺) constants derived from the analysis of the nine vibrational levels include: ωₑ = 388.2643 cm⁻¹, Bₑ = 0.1208034(33) cm⁻¹, and rₑ = 2.439687(14) Å. Excited state (A¹Σ⁺) constants determined include: Tₑ = 13932.7068(10) cm⁻¹, ωₑ = 339.1454(20) cm⁻¹, Bₑ = 0.1139895(38) cm⁻¹, and rₑ = 2.511601(17) Å. The spectra of calcium and strontium borohydrides were observed using low resolution laser spectroscopy. The spectra were assigned to the òA₁ - Ẋ²A₁ and Ḃ²E - Ẋ²A₁ transitions of CaBH₄ and SrBH₄. The vibrational frequencies of the metal-ligand stretch determined for CaBH₄ were 457 cm⁻¹ (Ẋ²A₁), 473 cm⁻¹ (Ā²A₁), and 465 cm⁻¹ (Ḃ²E). The corresponding SrBH4 frequencies were 399 cm⁻¹, 420 cm⁻¹, and 421 cm⁻¹. |
