• Penetrability and Hydraulic Conductivity of Dilute Sulfuric Acid Solutions in Selected Arizona Soils

      Miyamoto, S.; Ryan, J.; Bohn, H. L.; Department of Soils, Water and Engineering, College of Agriculture, The University of Arizona, Tucson 85721 (Arizona-Nevada Academy of Science, 1973-05-05)
      Measurements of penetrability and hydraulic conductivity in calcareous soils treated with a dilute sulfuric acid solution showed a severe decrease in conductivity with increasing concentrations over 1000 ppm. A slight decrease in penetrability was observed. Carbon dioxide evolution appeared to be responsible for flow reduction and temporary cessation at 10,000 ppm and 20,000 ppm. In sodic soils penetrability and conductivity increased markedly with sulfuric acid concentrations between 1,000 and 10,000 ppm. For a neutral soil, penetrability decreased with increasing sulfuric acid concentrations, and the stable conductivity for 500 to 5,000 ppm was higher than for water alone. The findings suggest that disposal of sulfuric acid concentrations greater than 1,000 ppm will result in plugging by carbon dioxide. In sodic soils the possibility exists of using sulfuric acid solutions for reclaiming salt and sodium-affected soils.
    • Salinity Problems of the Safford Valley: An Interdisciplinary Analysis

      Muller, Anthony B.; Department of Hydrology and Water Resources, University of Arizona, Tucson (Arizona-Nevada Academy of Science, 1973-05-05)
      A change in groundwater quality, averaging approximately +0.13 millimhos electrical conductivity and +35 ppm chloride per year, has been documented between 1940 and 1972 with data from ten long -term sample wells. The decrement in the water quality of the surficial aquifer seems to be attributable to four major mechanisms. An increase in salinity may be expected from leakage of saline water from the artesian aquifer. Such leakage would be stimulated by pumping- caused reduction of confining pressure, and by the puncture of the cap beds by deep wells. Water reaching the aquifer from natural recharge may contribute salts to the system. Such recharging water, if passed through soluble beds, could contribute to the salt. Lateral movement of water through similar deposits may be a contribution, and the concentration and infiltration of agricultural water could also add to aquifer salinity. The economic analysis of the Safford Valley, based on the modeling of a "Representative Farm" analog, indicates that cotton will remain economical to produce on the basis of the projected salinity trends, for a significant time beyond limits of prediction. The analysis indicates that the optimum salt-resistant crops for the area are being cultivated, and, of these, alfalfa will cease to be productive in large areas of the valley by 1990. The entire valley will not produce alfalfa for profit by 2040. The methodologies shown in the paper indicate how pumping influences salinity change and outline salinity control recommendations for the area.