Propentdyopent: the scaffold of a heme metabolite as an electron reservoir in transition metal complexes
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ROYAL SOC CHEMISTRYCitation
Propentdyopent: the scaffold of a heme metabolite as an electron reservoir in transition metal complexes 2016, 52 (39):6585 Chem. Commun.Journal
Chem. Commun.Rights
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Copyright is held by the author(s) or the publisher. If your intended use exceeds the permitted uses specified by the license, contact the publisher for more information.Collection Information
This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at repository@u.library.arizona.edu.Abstract
The dipyrrin-1,9-dione scaffold of heme metabolite propendyopent coordinates late transition metals (Co, Ni, Cu, and Zn) forming homoleptic, pseudo-tetrahedral complexes. Electrochemical and spectroscopic studies reveal that the monoanionic, bidentate ligands behave as electron reservoirs as the complexes reversibly host one or two ligand-based radicals.Note
Open Access Article--RSC Gold.ISSN
1359-73451364-548X
PubMed ID
27109437Version
Final published versionSponsors
We gratefully acknowledge Drs Jonathan Loughrey and Sue Roberts for assistance with initial electrochemical measurements and analysis of X-ray diffraction data, respectively. This work was supported by the University of Arizona and by the National Science Foundation ( CAREER grant 1454047 to E.T.).Additional Links
http://xlink.rsc.org/?DOI=C6CC01961GScopus Count
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Except where otherwise noted, this item's license is described as This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Copyright is held by the author(s) or the publisher. If your intended use exceeds the permitted uses specified by the license, contact the publisher for more information.