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Propentdyopent: the scaffold of a heme metabolite as an electron reservoir in transition metal complexes

dc.contributor.authorGautam, R.
dc.contributor.authorChang, T. M.
dc.contributor.authorAstashkin, A. V.
dc.contributor.authorLincoln, K. M.
dc.contributor.authorTomat, E.
dc.date.accessioned2016-12-15T20:40:22Z
dc.date.available2016-12-15T20:40:22Z
dc.date.issued2016
dc.identifier.citationPropentdyopent: the scaffold of a heme metabolite as an electron reservoir in transition metal complexes 2016, 52 (39):6585 Chem. Commun.en
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.pmid27109437
dc.identifier.doi10.1039/C6CC01961G
dc.identifier.urihttp://hdl.handle.net/10150/621713
dc.description.abstractThe dipyrrin-1,9-dione scaffold of heme metabolite propendyopent coordinates late transition metals (Co, Ni, Cu, and Zn) forming homoleptic, pseudo-tetrahedral complexes. Electrochemical and spectroscopic studies reveal that the monoanionic, bidentate ligands behave as electron reservoirs as the complexes reversibly host one or two ligand-based radicals.
dc.description.sponsorshipWe gratefully acknowledge Drs Jonathan Loughrey and Sue Roberts for assistance with initial electrochemical measurements and analysis of X-ray diffraction data, respectively. This work was supported by the University of Arizona and by the National Science Foundation ( CAREER grant 1454047 to E.T.).en
dc.language.isoenen
dc.publisherROYAL SOC CHEMISTRYen
dc.relation.urlhttp://xlink.rsc.org/?DOI=C6CC01961Gen
dc.rightsThis article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Copyright is held by the author(s) or the publisher. If your intended use exceeds the permitted uses specified by the license, contact the publisher for more information.en
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/
dc.titlePropentdyopent: the scaffold of a heme metabolite as an electron reservoir in transition metal complexesen
dc.typeArticleen
dc.contributor.departmentUniv Arizona, Dept Chem & Biochemen
dc.identifier.journalChem. Commun.en
dc.description.noteOpen Access Article--RSC Gold.en
dc.description.collectioninformationThis item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at repository@u.library.arizona.edu.en
dc.eprint.versionFinal published versionen
refterms.dateFOA2018-06-14T14:48:32Z
html.description.abstractThe dipyrrin-1,9-dione scaffold of heme metabolite propendyopent coordinates late transition metals (Co, Ni, Cu, and Zn) forming homoleptic, pseudo-tetrahedral complexes. Electrochemical and spectroscopic studies reveal that the monoanionic, bidentate ligands behave as electron reservoirs as the complexes reversibly host one or two ligand-based radicals.


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This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Copyright is held by the author(s) or the publisher. If your intended use exceeds the permitted uses specified by the license, contact the publisher for more information.
Except where otherwise noted, this item's license is described as This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Copyright is held by the author(s) or the publisher. If your intended use exceeds the permitted uses specified by the license, contact the publisher for more information.