Configuration-specific electronic structure of strongly interacting interfaces: TiOPc on Cu(110)
| dc.contributor.author | Maughan, Bret | |
| dc.contributor.author | Zahl, Percy | |
| dc.contributor.author | Sutter, Peter | |
| dc.contributor.author | Monti, Oliver L. A. | |
| dc.date.accessioned | 2018-01-31T17:54:55Z | |
| dc.date.available | 2018-01-31T17:54:55Z | |
| dc.date.issued | 2017-12-21 | |
| dc.identifier.citation | Configuration-specific electronic structure of strongly interacting interfaces: TiOPc on Cu(110) 2017, 96 (23) Physical Review B | en |
| dc.identifier.issn | 2469-9950 | |
| dc.identifier.issn | 2469-9969 | |
| dc.identifier.doi | 10.1103/PhysRevB.96.235133 | |
| dc.identifier.uri | http://hdl.handle.net/10150/626466 | |
| dc.description.abstract | We use low-temperature scanning tunneling microscopy in combination with angle-resolved ultraviolet and two-photon photoemission spectroscopy to investigate the interfacial electronic structure of titanyl phthalocyanine (TiOPc) on Cu(110). We show that the presence of two unique molecular adsorption configurations is crucial for a molecular-level analysis of the hybridized interfacial electronic structure. Specifically, thermally induced self-assembly exposes marked adsorbate-configuration-specific contributions to the interfacial electronic structure. The results of this work demonstrate an avenue towards understanding and controlling interfacial electronic structure in chemisorbed films even for the case of complex film structure. | |
| dc.description.sponsorship | National Science Foundation [CHE-1213243, CHE-1565497]; Arizona TRIF imaging fellowship; US DOE Office of Science Facility, at Brookhaven National Laboratory [DE-SC0012704]; US Department of Energy, Office of Basic Energy Sciences [DE-SC0016343] | en |
| dc.language.iso | en | en |
| dc.publisher | AMER PHYSICAL SOC | en |
| dc.relation.url | https://link.aps.org/doi/10.1103/PhysRevB.96.235133 | en |
| dc.rights | © 2017 American Physical Society. | en |
| dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | |
| dc.title | Configuration-specific electronic structure of strongly interacting interfaces: TiOPc on Cu(110) | en |
| dc.type | Article | en |
| dc.contributor.department | Univ Arizona, Dept Chem & Biochem | en |
| dc.contributor.department | Univ Arizona, Dept Phys | en |
| dc.identifier.journal | Physical Review B | en |
| dc.description.collectioninformation | This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at repository@u.library.arizona.edu. | en |
| dc.eprint.version | Final published version | en |
| refterms.dateFOA | 2018-04-25T18:25:58Z | |
| html.description.abstract | We use low-temperature scanning tunneling microscopy in combination with angle-resolved ultraviolet and two-photon photoemission spectroscopy to investigate the interfacial electronic structure of titanyl phthalocyanine (TiOPc) on Cu(110). We show that the presence of two unique molecular adsorption configurations is crucial for a molecular-level analysis of the hybridized interfacial electronic structure. Specifically, thermally induced self-assembly exposes marked adsorbate-configuration-specific contributions to the interfacial electronic structure. The results of this work demonstrate an avenue towards understanding and controlling interfacial electronic structure in chemisorbed films even for the case of complex film structure. |
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