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dc.contributor.authorWang, Alian
dc.contributor.authorLing, Zongcheng
dc.contributor.authorYan, Yuanchao
dc.contributor.authorMcEwen, Alfred S.
dc.contributor.authorMellon, Michael T.
dc.contributor.authorSmith, Michael D.
dc.contributor.authorJolliff, Bradley L.
dc.contributor.authorHead, James
dc.date.accessioned2019-09-12T20:30:54Z
dc.date.available2019-09-12T20:30:54Z
dc.date.issued2019-11-15
dc.identifier.citationWang, A., Ling, Z., Yan, Y., McEwen, A. S., Mellon, M. T., Smith, M. D., ... & Head, J. (2019). Subsurface Cl-bearing salts as potential contributors to recurring slope lineae (RSL) on Mars. Icarus, 333, 464-480.en_US
dc.identifier.issn0019-1035
dc.identifier.doi10.1016/j.icarus.2019.06.024
dc.identifier.urihttp://hdl.handle.net/10150/634179
dc.description.abstractWe report laboratory experimental results that support a brine-related hypothesis for the recurring slope lineae (RSL) on Mars in which the subsurface Cl-salts, i.e., hydrous chlorides and oxychlorine salts (HyCOS) are the potential source materials. Our experiments revealed that within the observed RSL temperature window T-RSL (250-300 K), the deliquescence of HyCOS could occur in relative humidity ranges (RH >= 22%-46%) much lower than those for hydrous (Mg, Fe)-sulfates (RH >= 75%-96%). In addition, we demonstrated that the RH values kept by common HyCOS and hydrous sulfates in enclosures have a general trend as RHsulfates > RHperchlorates > RHchlorides (with same type of cation) in wide T range. It means that the required RH range for a Cl-bearing salt to deliquescence can be satisfied by a co-existing salt of different type, e.g., in the subsurface layers of mixed salts on Mars. Furthermore, we found a strong temperature dependence of the deliquescence rates for all tested HyCOS, e.g., a duration of 1-5 sols for all HyCOS at the high end (300 K) of T-RSL, and of 20-70 sols for all tested HyCOS (except NaClO4 center dot H2O) at the low end (250 K) of T-RSL, which is consistent with the observed seasonal behavior of RSL on Mars. From a mass-balance point of view, the currently observed evidences on Mars do not support a fully-brine-wetted track model, thus we suggest a brine-triggered granular-flow model for the most RSL. Considering the recurrence of RSL in consecutive martian years, our experimental results support the rehydration of remnant HyCOS layers during a martian cold season through H2O vapor-to-salt direct interaction. We found that the evidences of HyCOS rehydration under Mars relevant P-T-RH conditions are detectable in a few minutes by in situ Raman spectroscopy. This rehydration would facilitate the recharge of H2O back into subsurface HyCOS, which could serve as the source material to trigger RSL in a subsequent warm season. The major limiting factor for this rehydration is the H2O supply, i.e., the H2O vapor density carried by current Mars atmospheric circulation and the diffusion rate of H2O vapor into the salt-rich subsurface in a cold season. In a worst-case scenario, these H2O supplies can support a maximum increase of hydration degrees of two for totally dehydrated HyCOS, whereas the full rehydration of subsurface HyCOS layers can be easily reached during a > 30 degrees obliquity period that has H2O vapor density 10 x to 20 x times the value of current obliquity. Overall, our results imply the existence of a large amount of Cl-bearing salts in the subsurface at RSL sites.en_US
dc.description.sponsorshipNASA MoO project [06-Scout06-0027-, 49137-NRA 1295053]; McDonnell Center for the Space Sciences at Washington University in St Louis; Shandong University in China; National Natural Science Foundation of China [41473065, JQ201511, 41373068, 41490634]en_US
dc.language.isoenen_US
dc.publisherACADEMIC PRESS INC ELSEVIER SCIENCEen_US
dc.rightsCopyright © 2019 Elsevier Inc. All rights reserved.en_US
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/
dc.subjectMarsen_US
dc.subjectHydrous Cl-bearing saltsen_US
dc.subjectDeliquescenceen_US
dc.subjectRehydrationen_US
dc.subjectRaman spectroscopyen_US
dc.subjectRecurring slope lineaeen_US
dc.titleSubsurface Cl-bearing salts as potential contributors to recurring slope lineae (RSL) on Marsen_US
dc.typeArticleen_US
dc.contributor.departmentUniv Arizona, Lunar & Planetary Laben_US
dc.identifier.journalICARUSen_US
dc.description.note24 month embargo; published online: 15 November 2019en_US
dc.description.collectioninformationThis item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at repository@u.library.arizona.edu.en_US
dc.eprint.versionFinal accepted manuscripten_US
dc.source.volume333
dc.source.beginpage464-480


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