• From the Guest Editor

      Carmi, Israel (Department of Geosciences, The University of Arizona, 2001-01-01)
    • Is Classical Acid-Alkali-Acid Treatment Responsible for Contamination? An Alternative Proposition

      Hatté, Christine; Morvan, Jean; Noury, Claude; Paterne, Martine (Department of Geosciences, The University of Arizona, 2001-01-01)
      It is well known that, during the widely used AAA pretreatment (de Vries and Barendsen 1954), alkali treatment is responsible for the incorporation of modern carbon due to the precipitation of atmospheric CO2 as carbonate. Until now, the last step of the experiment, consisting in acid treatment (most of the time with hydrochloric acid) was considered to be sufficient to eliminate all of lab contamination. But wood, peat and sediment present a complex molecular structure. During radiocarbon chemical treatments, functional groups still present in the molecules are likely to form ionic bonds with “modern” carbonates. These new chemical bonds resist a “classical” acid treatment and are responsible for rejuvenation. This short paper presents preliminary results for two common 14C cases: rejuvenation of a 0.4 pMC wood and of an Oxygen Isotope Stage 3 (OIS3) paleosol. For both cases, contamination due to incorporation of modern carbon during chemical treatment is evaluated and an alternative protocol is proposed.
    • Is Comparability of 14C Dates an Issue?: A Status Report on the Fourth International Radiocarbon Intercomparison

      Bryant, C.; Carmi, I.; Cook, G. T.; Gulliksen, S.; Harkness, D. D.; Heinemeier, J.; McGee, E.; Naysmith, P.; Possnert, G.; Scott, E. M.; et al. (Department of Geosciences, The University of Arizona, 2001-01-01)
      For more than 15 years, the radiocarbon community has participated in a series of laboratory intercomparisons in response to the issue of comparability of measurements as perceived within the wider user communities (Scott et al. 1990; Rozanski et al. 1992; Gulliksen and Scott 1995; Scott et al. 1997). In this report, we provide an update on the current 14C laboratory intercomparison and reflect on future issues linked to the laboratory intercomparison program, not least those resulting from a significant growth in the number of accelerator mass spectrometry (AMS) facilities providing routine dating of small samples (milligram size).
    • Marine Radiocarbon Reservoir Effect in the Western North Pacific Observed in Archaeological Fauna

      Yoneda, Minoru; Hirota, Masashi; Uchida, Masao; Uzawa, Kazuhiro; Tanaka, Atsushi; Shibata, Yasuyui; Morita, Masatoshi (Department of Geosciences, The University of Arizona, 2001-01-01)
      Faunal remains originating from terrestrial and marine mammals, and belonging to the same archaeological deposits were compared to evaluate the marine radiocarbon reservoir ages around the Hokkaido island, Japan. From five shell middens of different ages from the Jomon period (4900 BP) to the Ainu cultural period (800 BP), 107 animal bone samples were selected for radiocarbon measurements. The apparent age differences between Japanese deer and northern fur seal showed the clear effect of deep-water upwelling in this region. Our data showed relatively stable age differences from 4500 BP to 800 BP, with an estimated Delta-R values around 380 14C yr. Results are consistent with previous estimation based on simulation models and oceanographic properties.
    • New Methods and Critical Aspects in Bayesian Mathematics for 14C Calibration

      Steier, Peter; Rom, Werner; Puchegger, Stephan (Department of Geosciences, The University of Arizona, 2001-01-01)
      The probabilistic radiocarbon calibration approach, which largely has replaced the intercept method in 14C dating, is based on the so-called Bayes' theorem (Bayes 1763). Besides single-sample calibration, Bayesian mathematics also supplies tools for combining 14C results of many samples with independent archaeological information such as typology or stratigraphy (Buck et al. 1996). However, specific assumptions in the "prior probabilities", used to transform the archaeological information into mathematical probability distributions, may bias the results (Steier and Rom 2000). A general technique for guarding against such a bias is "sensitivity analysis", in which a range of possible prior probabilities is tested. Only results that prove robust in this analysis should be used. We demonstrate the impact of this method for an assumed, yet realistic case of stratigraphically ordered samples from the Hallstatt period, i.e. The Early Iron Age in Central Europe.
    • Northwest Pacific Marine Reservoir Correction Estimated from Annually Banded Coral from Ishigaki Island, Southern Japan

      Hideshima, Shinichiro; Matsumoto, Eiji; Abe, Osamu; Kitagawa, Hiroyuki (Department of Geosciences, The University of Arizona, 2001-01-01)
      We assessed marine reservoir age R(t) for the costal area of the northwest Pacific using radiocarbon measurements of the annually banded coral core (Porites sp) collected on Ishigaki Island in southern Japan. Reservoir age R(t) during the early 1900s at the Pacific coast of Ishigaki Island ranged between 290 and 455 14C yr, with a weighted mean of 355 +/25 14C yr (n=5, +/1 sigma). The regional-specific ∆R, defined as 14C age difference of regional and world ocean surface layer, was 35 +/25 14C yr (n=5, +/1 sigma) on average and increased between 1900 and 1950.
    • Preliminary Estimate of the Reservoir Age in the Lagoon of Venice

      Zoppi, Ugo; Albani, A.; Ammerman, A. J.; Hua, Quan; Lawson, E. M.; Serandrei Barbero, R. (Department of Geosciences, The University of Arizona, 2001-01-01)
      The Lagoon of Venice was formed about 6000 years ago due to the marine transgression associated with the late Pleistocene sea level rise. Already by the time of the Republic of Venice (727-1797 AD) it was recognized that the future of the city and its many historical buildings was strongly correlated with the future of the lagoon itself. During the centuries many engineering projects such as modification of the fluvial systems, construction of coastal barriers, and dredging of navigation channels were carried out to preserve the lagoonal environment. The present-day lagoon is the result of all these processes and covers an area of 540 km2 with an average depth of 0.6 m. A series of radiocarbon age determinations carried out on material obtained from cores collected in the Lagoon of Venice indicate within the sedimentary units the existence of a number of discontinuities and slumping events due to the highly active lagoonal environment. The evaluation of data obtained from a variety of different materials—both terrestrial and marine—allowed us to determine for the first time the marine reservoir effect in the lagoon of Venice. The discussion includes a comparison with other relevant measurements and a possible explanation to the relatively high reservoir age (1200-1300 yr).
    • Preparation of Graphite Targets in the Gliwice Radiocarbon Laboratory for AMS 14C Dating

      Czernik, Justyna; Goslar, Tomasz (Department of Geosciences, The University of Arizona, 2001-01-01)
      A line for preparation of graphite targets for accelerator mass spectrometry (AMS) radiocarbon dating has been built in the Gliwice 14C Laboratory. The AMS 14C measurements of our targets are performed in the Leibniz-Labor fur Altersbestimmung, Kiel, Germany. The quality of our line has been tested in two series of AMS 14C measurements of background and Ox-II standard samples and by measurements of the amount of CO2 released during combustion of sample-free quartz tubes. Most background contamination in the first series was introduced during combustion, which has been greatly reduced by baking quartz tubes vacuum-sealed with CuO and Ag. The residual contamination (ca. 1.5 micrograms C) seems to come mostly from the quartz tubes themselves. At present, most of the contamination of the background is introduced during graphitization. The reproducibility of background preparations is satisfactory, especially for samples larger than 1.5 mg, when it is better than +/0.09 pMC. Despite still significant contamination with low-14C carbon during the graphitization process (corresponding to 1.2 +/0.2% of 14C-free carbon), the good reproducibility of the results allows us to use our line in routine 14C dating.
    • Pretreatment of Iron Artifacts at SNU-AMS

      Cheoun, M. K.; Kim, J. C.; Kang, J.; Kim, I. C.; Park, J. H.; Song, Y. M. (Department of Geosciences, The University of Arizona, 2001-01-01)
      We present the current status of accelerator mass spectrometry (AMS) dating of iron artifacts at Seoul National University (SNU). In ancient iron production, charcoal was widely used as carbon for the smelting process, whereas coal is used in modern times. If reliable data could be obtained from carbon by using AMS, ancient iron artifacts could be traced to their production age. In normal acid treatment, it is not easy to extract carbon due to its colloidal property. The negative charge property of the carbon colloid, however, makes it possible for it to be precipitated with positive ions by dissolving the iron chemically. An extraction yield of the carbon incorporated in modern cast iron of about 70% is attained. More refined methods to increase the extraction rate are under progress for archaeological applications.
    • PRIME Lab Sample Handling and Data Analysis for Accelerator-Based Biomedical Radiocarbon Analysis

      Hillegonds, Darren J.; Record, Rae; Rickey, Frank A.; Badylak, Steve; Jackson, George S.; Simmons-Byrd, Abby; Elmore, David; Lipschutz, Michael E. (Department of Geosciences, The University of Arizona, 2001-01-01)
      Processing and measurement of 200 biomedical samples has provided an opportunity to better understand the characteristics of accelerator mass spectrometry (AMS) analysis of such samples. We have utilized established procedures (Vogel 1992) and developed new methods for handling various biological samples. We have included secondary standards of known isotope ratio for all assays. A method of determining maximum precision for each unknown sample value is also reported. The presented data are an update of the ongoing radiocarbon AMS biomedical program at Purdue University.
    • Progress at the Seoul National University AMS Facility

      Kim, J. C.; Park, J. H.; Kim, I. C.; Lee, C.; Cheoun, M. K.; Kang, J.; Song, Y. M. (Department of Geosciences, The University of Arizona, 2001-01-01)
      The accelerator mass spectrometry facility at the Seoul National University (SNU-AMS) was completed in December 1998 and a report was presented at the Vienna AMS conference in September 1999. At the conference, we described the basic components of our accelerator system and reported the results of the performance test. Since then, extensive testing of the accuracy and reproducibility of the system has been carried out, and about 200 unknown samples have been measured so far. We obtained a precision of 4‰ for modern samples, and an accuracy of approximately 40 yr was demonstrated by analyzing samples that were previously dated with a conventional technique and by other AMS laboratories. We present these results here, together with detailed descriptions of our data-taking and analysis procedures.
    • Progress in Radiocarbon Target Preparation at the ANTARES AMS Centre

      Hua, Q.; Jacobsen, G. E.; Zoppi, U.; Lawson, E. M.; Williams, A. A.; McGann, M. J. (Department of Geosciences, The University of Arizona, 2001-01-01)
      We present routine methods of target preparation for radiocarbon analysis at the ANTARES Accelerator Mass Spectrometry (AMS) Centre, as well as recent developments which have decreased our procedural blank level and improved our ability to process small samples containing less than 200 micrograms of carbon. Routine methods of 14C sample preparation include sample pretreatment, CO2 extraction (combustion, hydrolysis and water stripping) and conversion to graphite (graphitization). A new method of cleaning glassware and reagents used in sample processing, by baking them under a stream of oxygen, is described. The results show significant improvements in our procedural blanks. In addition, a new graphitization system dedicated to small samples, using H2/Fe reduction of CO2, has been commissioned. The technical details of this system, the graphite yield and the level of fractionation of the targets are discussed.
    • Protocol Development for Purification and Characterization of Sub-Fossil Insect Chitin for Stable Isotopic Analysis and Radiocarbon Dating

      Hodgins, Gregory W. L.; Thorpe, J. L.; Coope, G. R.; Hedges, Robert E. M. (Department of Geosciences, The University of Arizona, 2001-01-01)
      Reliable radiocarbon dating depends upon well-defined samples. We have been investigating whether or not reliable 14C dates can be obtained directly from sub-fossil insect cuticle or biochemical fractions derived from it. Initial carbon and nitrogen stable isotope measurements on sub-fossil insect chitin from species with known feeding behaviors found within a single site (St Bees, Cumbria) clustered in a manner reminiscent of trophic level effects seen in terrestrial ecosystems. Although this finding implied some chemical stability, the measurement of CN ratios from the same samples indicated compositional variability. In addition, 14C dates obtained from these same samples were different from dates obtained from plant macrofossils found at the same depth. We have experimented with protocols designed to biochemically reduce chitin to its principle carbohydrate component glucosamine with the aim of using this compound to generate reliable 14C dates. Solvent extractions of sub-fossil chitin were carried out to remove both endogenous and exogenous lipid-soluble materials. Base hydrolysis reactions designed to extract polypeptides retained surprisingly high levels of contaminating amino acids. Proteinase K enzyme treatment had little affect on the level of amino acid contamination. Strong acid hydrolysis reactions designed to depolymerize chitin to glucosamine yielded only 5% glucosamine. Clearly alternative methods of chitin depolymerization must be identified before the purification and 14C dating of glucosamine from sub-fossil chitin becomes practical.
    • Radiocarbon and Dendrochronological Dating of Logboats from Poland

      Pazdur, Anna; Krąpiec, Marek; Michczyński, Adam; Ossowski, Waldemar (Department of Geosciences, The University of Arizona, 2001-01-01)
      The earliest dating of samples taken from logboats found in the area of Poland was done at the Gliwice Radiocarbon Laboratory in the late 1970s and early 1980s. After a 10-year break, the study of their chronology was renewed. The 14C dates (56) include all previously published and new, unpublished results obtained during last several years. Here, we discuss and provide probabilistic interpretation of the calendar age of the dated boats. The calibration of 14C dates was done with the OxCal program for dates less than 300 BP, and with the GdCALIB program for all remaining dates. In distribution of calibrated dates we find a lack of samples between the ages of around 800 BC and 300 AD. This result is surprising and differs from results observed for Central Europe. The remaining age ranges, with high frequency of dates, are in good coincidence with similar periods obtained for Central Europe. Tree-ring dating of oak logboats was carried out on 60 growth sequences, dated against standard chronologies defined for the area of Poland. The results of 14C dating and tree-ring analyses give consistent chronologies.
    • Radiocarbon Dating of Single Compounds Isolated from Pottery Cooking Vessel Residues

      Stott, A. W.; Berstan, R.; Evershed, P.; Hedges, Robert E. M.; Bronk Ramsey, Christopher; Humm, M. J. (Department of Geosciences, The University of Arizona, 2001-01-01)
      We have developed and demonstrated a practical methodology for dating specific compounds (and octadecanoic or stearic acid—C18:0—in particular) from the lipid material surviving in archaeological cooking pots. Such compounds may be extracted from about 10 g of cooking potsherd, and, after derivatization, can be purified by gas chromatography. To obtain sufficient material for precise dating repetitive, accumulating, GC separation is necessary. Throughout the 6000-year period studied, and over a variety of site environments within England, dates on C18:0 show no apparent systematic error, but do have a greater variability than can be explained by the errors due to the separation chemistry and measurement process alone. This variability is as yet unexplained. Dates on C16:0 show greater variability and a systematic error of approximately 100-150 years too young, and it is possible that this is due to contamination from the burial environment. Further work should clarify this.
    • Radiocarbon Dating of Wood Using Different Pretreatment Procedures: Application to the Chronology of Rotoehu Ash, New Zealand

      Santos, Guaciara M.; Bird, M. I.; Fifield, L. Keith; Alloway, B. V.; Chappell, J.; Hausladen, P. A.; Arneth, A. (Department of Geosciences, The University of Arizona, 2001-01-01)
      We compare radiocarbon accelerator mass spectrometry (AMS) ages of wood samples subjected to a conventional acid-base-acid pretreatment with stepped combustion (ABA-SC) with results from the same samples subjected to an acid-base-wet oxidation pretreatment with stepped combustion (ABOX-SC) and cellulose extraction with stepped combustion (CE-SC). The ABOX-SC procedure has been shown previously to lead to lower backgrounds for old charcoal samples. Analyses of relatively uncontaminated " 14C-dead" samples of wood suggest that backgrounds of 0.11 +/0.04 pMC are obtainable for both the ABOX-SC and ABA-SC procedures. Where wood is significantly contaminated the ABOX-SC technique provides significantly better decontamination than either the ABA-SC technique or cellulose extraction alone, although CE-SC can produce comparably low backgrounds to the ABOX-SC procedure. We also report the application of the ABOX-SC, ABA-SC and CE-SC procedures to wood samples associated with the chronologically controversial Rotoehu Ash eruption, New Zealand. New 14C-AMS dates from wood sampled from below the Rotoehu Ash span an age range of 43-50 ka BP consistent with recently presented OSL dates of 42-44 ka obtained for palaeosols beneath the ash.
    • Radiocarbon Measurements of Tree Rings from 14 ka Huon Pine

      Lange, Todd; Barbetti, M.; Donahue, Douglas J. (Department of Geosciences, The University of Arizona, 2001-01-01)
      We have measured the radiocarbon content of tree rings from a section of Huon pine retrieved from Tasmania. The sample was divided into 39 five-ring sub-samples covering a period of 194 years. Radiocarbon ages of each of these sub-samples was determined by making four measurements of each sub-sample at the Arizona AMS laboratory (Table 1). The resulting 1-sigma precisions are about 0.5%. A comparison of our data with the appropriate curve in INTCAL98 indicates that the calendar age of our sample is close to 14,000 cal BP. Using this age calibration, we have constructed a plot of Delta-14C versus assumed calendar age. This plot shows an essentially constant value over the youngest 125 rings of our sample. Over the oldest 75 yr of the sample, the Delta-14C curve exhibits three fluctuations, the largest of which is about 65 per mil. The time of the peaks in the Huon-pine 14C curve corresponds approximately with the European Bolling/Allerod climatic event. Work is in progress to extend the data 100 yr more toward older ages.
    • Radiocarbon Reservoir Correction Ages in the Peter the Great Gulf, Sea of Japan, and Eastern Coast of the Kunashir, Southern Kuriles (Northwestern Pacific)

      Kuzmin, Yaroslav V.; Burr, George S.; Jull, A. J. Timothy (Department of Geosciences, The University of Arizona, 2001-01-01)
      The radiocarbon reservoir age correction values (R) for the Russian Far East are estimated as 370 +/26 yr for the northwestern Sea of Japan, and 711 +/46 yr for the southern Kurile Islands.
    • Sample Preparation of Dissolved Organic Carbon in Groundwater for AMS 14C Analysis

      Burr, George S.; Thomas, J. M.; Reines, D.; Jeffrey, D.; Courtney, C.; Jull, A. J. Timothy; Lange, Todd (Department of Geosciences, The University of Arizona, 2001-01-01)
      This study describes a sample preparation technique used to isolate dissolved organic carbon (DOC) in groundwater for radiocarbon analysis using accelerator mass spectrometry (AMS). The goal of the work is to improve our ability to determine groundwater residence times based on 14C measurements of the DOC fraction in groundwater. Water samples were collected from carbonate and volcanic rock aquifers in southern Nevada. Multiple measurements of total dissolved organic carbon (TDOC) in groundwater from one site are used to demonstrate the reproducibility of the analytical procedure. The reproducibility of the method is about one percent (1sigma) for a 0.5 mg sample. The procedural blank for the same size sample contains about 1 percent modern carbon (pMC).