Radiocarbon, Volume 41 (1999): Recent submissions
Now showing items 21-40 of 45
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Radiocarbon UpdatesDepartment of Geosciences, The University of Arizona, 1999-01-01
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Radiocarbon Distribution in Northwest Belarus Near the Ignalina Nuclear Power PlantSince 1994, the Institute of Geological Sciences has undertaken an environmental monitoring program to measure radiocarbon levels in territory adjacent to active nuclear power plants (NPP). We determined 14C concentrations in natural objects from areas contiguous to Ignalina NPP as well as 14C background concentration in areas remote from the NPP. In the environs of the Ignalina station comparatively elevated levels of 14C were observed in vegetation and waters of Lake Drisvyaty. This appears to be a consequence of release of carbon radioisotope into the atmosphere and probably into waters of the lake during operation of the nuclear reactor.
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Radiocarbon LaboratoriesDepartment of Geosciences, The University of Arizona, 1999-01-01
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Radiocarbon Dating of "Old" Charcoal Using a Wet Oxidation, Stepped-Combustion ProcedureWe present results that validate a new wet oxidation, stepped-combustion procedure for dating "old" charcoal samples. An acid-base-wet oxidation (ABOX) pretreatment procedure has been developed that is used in place of the conventional acid-base-acid (ABA) pretreatment. Combustions and graphitizations are performed in a vacuum line that is insulated from the atmosphere by a second backing vacuum to eliminate the risk of atmospheric leakage into the line at any stage of the procedure. Combustions are performed at 3 temperatures (330 degrees C, 630 degrees C and 850 degrees C) with a graphite target produced from the CO2 evolved during each combustion step. In this way, the removal of any contamination can be monitored, and a high degree of confidence can be placed on the final age. The pretreatment, combustion, graphitization, and measurement blank for the procedure, based on the analysis of a "radiocarbon-dead" graphite, is 0.5 +/0.5 micrograms C (1sigma, n = 14), equivalent to 0.04 +/0.02 pMC or an "age" of approximately 60 ka for a 1 mg graphite target. Analyses of a "radiocarbon-dead" natural charcoal after ABOX pretreatment and stepped combustion suggest that the total blank (including contamination not removed by pretreatment) may be higher than for graphite, ranging up to 0.10 +/0.02 pMC. Additional experiments confirm good agreement with accepted values for the international low14C "New Kauri" standard (0.16-0.25 pMC). They also confirm excellent reproducibility, with 3 separate dates on different aliquots of a charcoal sample from Ngarrabullgan Cave (Queensland, Australia) ranging from 35.2 to 35.5 ka 14C BP. It is also demonstrated that the ABOX pretreatment, in conjunction with the new vacuum line described here, is able to remove contamination not removed by the conventional ABA pretreatment, suggesting that the technique can be used to produce reliable 14C dates on charcoal up to at least 50 ka.
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Radiocarbon Dates from Northern MongoliaSince 1996, the Mongolian-American Expedition to Northern Mongolia has been excavating in the Egiin Gol Valley. The goal of this research has been to examine the competing hypotheses explaining the emergence of pastoral nomadism and the evolution of nomadic complexity. The chronological placement of burials and sites in the survey area has been a key facet of this research. At present, these investigations have generated 10 radiocarbon dates from archaeological contexts. Presented here are the previously unpublished 14C dates and some comments on their significance.
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Radiocarbon Calibration by the Date Distribution MethodA method is presented for calibrating radiocarbon ages based on statistical analysis of a large number of randomly distributed dates. One interesting feature of this method is that it is internal; that is, it allows one to extend a known calibration curve further back in time by using only 14C dates, with no reference to any other dating technique. A serious difficulty in implementing this method lies in assembling a sample of dates with the correct statistical properties.
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Radiocarbon Analysis of Pinus lagunae Tree Rings: Implications for Tropical DendrochronologyA promising species for tropical dendrochronology is Pinus lagunae, a pine tree found in Baja California Sur (Mexico) around lat 23.5 degrees N. In 1995, we sampled a total of 27 wood cores from 13 Pinus lagunae trees in Sierra La Victoria (23 degrees 36'N, 109 degrees 56'W), just north of Sierra La Laguna, at an elevation of 1500-1600 m. Selected trees were locally dominant, but their ring-width patterns could not be crossdated. To test the hypothesis that visible growth layers in Pinus lagunae are formed annually, we measured radiocarbon amounts in individual rings by means of accelerator mass spectrometry (AMS). Twenty-three 14C measurements were used to trace the location of the 1963-64 "bomb spike" in 3 wood increment cores. By comparing the location of that Delta-14C extreme with the number of visible radial wood increments, it was possible to conclude that 2 cores had a number of locally absent rings, while the 3rd one included a few years with more than one growth layer. Therefore, ring-width patterns of sampled Pinus lagunae were not consistent from one tree to another, most likely because of climatic regime in combination with microsite features. While the possibility of generating Pinus lagunae tree-ring chronologies cannot entirely be ruled out, the development of dendrochronological proxy records of climate from coniferous species in tropical North America should focus on species and sites that experience a more pronounced seasonality.
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Radiocarbon Age Anomalies in Land Snail Shells from Texas: Ontogenetic, Individual, and Geographic Patterns of VariationAccelerator mass spectrometric (AMS) radiocarbon analyses of live-collected, prebomb samples of shell carbonates of the land snails Rabdotus dealbatus and R. Alternatus from Texas were carried out to quantify the characteristic age anomalies of land snails from limestone areas. Age anomalies are similar for the two species; they average +700 yr and vary by +/180 yr (1 sigma) among samples. Serial analysis of 1 shell reveals a significant ontogenetic trend in 14C age anomalies, with older apparent ages (up to 1200 yr) in the apical part of the shell and younger and uniform ages in the last whorl. No trend in age anomalies was found across a broad range of rainfall conditions (from 300 to 1000 mm mean annual rainfall).
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Oceanic Radiocarbon Between Antarctica and South Africa Along WOCE Section 16 at 30 Degrees EAccelerator mass spectrometry (AMS) radiocarbon measurements were made on 120 samples collected between Antarctica and South Africa along 30 degrees E during the WOCE-France CIVA1 campaign in February 1993. Our principal objective was to complement the Southern Ocean's sparse existing data set in order to improve the 14C benchmark used for validating ocean carbon-cycle models, which disagree considerably in this region. Measured 14C is consistent with the theta -S characteristics of CIVA1. Antarctic Intermediate Water (AAIW) forming north of the Polar Front (PF) is rich in 14C, whereas surface waters south of the PF are depleted in 14C. A distinct old 14C signal was found for the contribution of the Pacific Deep Water (PDW) to the return flow of Circumpolar Deep Waters (CDW). Comparison to previous measurements shows a 14C decrease in surface waters, consistent with northward displacement of surface waters, replacement by old deep waters upwelled at the Antarctic Divergence, and atmospheric decline in 14C. Conversely, an increase was found in deeper layers, in the AAIW. Large uncertainties, associated with previous methods for separating natural and bomb 14C when in the Southern Ocean south of 45 degrees S, motivated us to develop a new approach that relies on a simple mixing model and on chlorofluorocarbon (CFC) measurements also taken during CIVA1. This approach leads to inventories for CIVA1 that are equal to or higher than those calculated with previous methods. Differences between old and new methods are especially high south of approximately 55 degrees S, where bomb 14C inventories are relatively modest.
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Dating Organic Temper of Ceramics by AMS: Sample Preparation and Carbon EvaluationWe describe a new methodology for separating organic temper from archaeological ceramics from Brazilian Amazonia. These experimental procedures were designed to directly date ceramic samples by accelerator mass spectrometry (AMS). An evaluation of the total carbon indicates the samples' potential for dating.
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Comments on "America's Oldest Basketry"A recent publication on directly dated basketry specimens from the western United States (Berger et al. 1998, Radiocarbon 40(2):615-20) contained some misleading information, and in a few cases discussed radiocarbon ages from unacknowledged sources. We provide the missing original citations along with some clarifications. We focus especially on the age of distinctive Fort Rock and Multiple Warp-style sandals, for which we provide additional previously unreported 14C ages. Direct dates on fibers from Fort Rock sandals from 3 different sites range in age from 10,500 cal BP to about 9200 cal BP. Contextual evidence suggests that Multiple Warp sandals may date as early as 6600 cal BP, but the few directly dated specimens are less than 1000 yr old.
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Comparing Carbonate and Organic AMS-14C Ages in Lake Abiyata Sediments (Ethiopia): Hydrochemistry and Paleoenvironmental ImplicationsWe studied a 12.6-m-long sequence from Lake Abiyata (Central Ethiopia) to establish a reliable and accurate chronology for use in global paleoclimatic reconstructions. The 26 accelerator mass spectrometry radiocarbon (AMS 14C) ages, performed on carbonates and organic matter, define 2 parallel chronologies, representing the complete Holocene period. However, these chronologies show a significant discrepancy from 500 to 900 BP in depth; ages obtained on carbonates were always older than those on organic matter. The hydrogeological and geochemical behavior of the Lake Abiyata basin has shed light on this discrepancy. We found that the carbonate crystallization is due mainly to the mixing of lake waters with ground-waters from the multi-layered aquifer contained in the 600-m-thick basement of the lake. The 14C activity of total dissolved inorganic carbon (TDIC) measured by AMS from bottom and surface lake waters (111.4 and 111.8 pMC, respectively) confirms that the mixing occurs at the water-sediment interface. This evidence of groundwater participation in the carbonate crystallization calls into question the current paleoclimatic reconstructions based on inorganic carbonates in lakes. Specific attention should thus be given to the respective proportions of each end-member in the mixing for the quantitative estimation of the groundwater input. This will help to validate the paleoenvironmental reconstructions and to highlight an eventual diagenetical evolution of inorganic carbonates during burial, via the study of pore waters.
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Chronology of Vegetation and Paleoclimatic Stages of Northwestern Russia During the Late Glacial and HoloceneWe have studied 6 reference sections of bog and lake sediments in the Leningrad and Novgorod provinces to develop a geochronological scale for vegetational and paleoclimatic changes in northwestern Russia during the Late Glacial and Holocene. Every 10-cm layer along the peat and gyttja sections (4-8.5 m thick) was investigated palynologically and the great majority of them were radiocarbon dated. Using the data obtained, standard palynological diagrams were plotted and vegetation history reconstructed. The palynozones indicated on the diagrams were related to the climatic periods and subperiods (phases) of the Blytt-Sernander scheme. On the basis of 230 14C dates obtained, we derived the geochronology of climatic periods and phases, as well as the chronology for the appearance and areal distribution of forest-forming tree species. The uppermost peat layers were dated by using the "bomb effect". We compared the stages of Holocene vegetation and paleoclimatic changes discovered for the Leningrad and Novgorod provinces with the those obtained for Karelia, which we had studied earlier using the same methodology.
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Changes in 14C Activity over Time During Vacuum Distillation of Carbon from Rock Pore WaterThe radiocarbon activity of carbon collected by vacuum distillation from a single partially saturated tuff began to decline after approximately 60% of the water and carbon had been extracted. Disproportionate changes in 14C activity and delta-13C during distillation rule out simple isotopic fractionation as a causative explanation. Additional phenomena such as matrix diffusion and ion exclusion in micropores may play a role in altering the isotopic value of extracted carbon, but neither can fully account for the observed changes. The most plausible explanation is that distillation recovers carbon from an adsorbed phase that is depleted in 14C relative to DIC in the bulk pore water.
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Change of Diet of the Greenland Vikings Determined from Stable Carbon Isotope Analysis and 14C Dating of Their BonesBone samples from the Greenland Viking colony provide us with a unique opportunity to test and use 14C dating of remains of humans who depended upon food of mixed marine and terrestrial origin. We investigated the skeletons of 27 Greenland Norse people excavated from churchyard burials from the late 10th to the middle 15th century. The stable carbon isotopic composition (delta-13C) of the bone collagen reveals that the diet of the Greenland Norse changed dramatically from predominantly terrestrial food at the time of Eric the Red around AD 1000 to predominantly marine food toward the end of the settlement period around AD 1450. We find that it is possible to 14C-date these bones of mixed marine and terrestrial origin precisely when proper correction for the marine reservoir effect (the 14C age difference between terrestrial and marine organisms) is taken into account. From the dietary information obtained via the delta-13C values of the bones we have calculated individual reservoir age corrections for the measured 14C ages of each skeleton. The reservoir age corrections were calibrated by comparing the 14C dates of 3 highly marine skeletons with the 14C dates of their terrestrial grave clothes. The calibrated ages of all 27 skeletons from different parts of the Norse settlement obtained by this method are found to be consistent with available historical and archaeological chronology. The evidence for a change in subsistence from terrestrial to marine food is an important clue to the old puzzle of the disappearance of the Greenland Norse, obtained here for the first time by measurements on the remains of the people themselves instead of by more indirect methods like kitchen-midden analysis.
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Calculation of Past Dead Carbon Proportion and Variability by the Comparison of AMS 14C and TIMS U/Th Ages on Two Holocene StalagmitesTwenty-two radiocarbon activity measurements were made by accelerator mass spectrometry (AMS) on 2 Holocene stalagmites from Belgium (Han-stm lb) and from southwest France (Vil-stm lb). Sixteen thermal ionization mass spectrometric (TIMS) U/Th measurements were performed parallel to AMS analyses. The past dead carbon proportion (dcp) due to limestone dissolution and old soil organic matter (SOM) degradation is calculated with U/Th ages, measured calcite 14C activity and atmospheric 14C activity from the dendrochronological calibration curves. Results show that the dcp is different for the 2 stalagmites: between 10,800 and 4780 yr from present dcp = 17.5% (sigma = 2.4; n = 10) for Han-stm lb and dcp = 9.4% (sigma = 1.6; n = 6) between 3070 and 520 yr for Vil-stmlb. Despite a broad stability of the dcp during the time ranges covered by each sample, a slight dcp increase of about 5.0% is observed in the Han-stmlb sample between 8500 and 5200 yr. This change is synchronous with a calcite delta-13C increase, which could be due to variation in limestone dissolution processes possibly linked with a vegetation change. The dcp and delta-13C of the 2 studied samples are compared with 5 other modern stalagmites from Europe. Results show that several factors intervene, among them: the vegetation type, and the soil saturation leading to variable dissolution process systems (open/closed). The good correlation (R2 = 0.98) between the U/Th ages and the calibrated 14C ages corrected with a constant dcp validates the 14C method. However, the dcp error leads to large 14C age errors (i.e. 250-500 yr for the period studied), which is an obstacle for both a high-resolution chronology and the improvement of the 14C calibration curves, at least for the Holocene.
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Author Index Volume 41, 1999Department of Geosciences, The University of Arizona, 1999-01-01