• 13C Variation in Limestone on an Aquifer-Wide Scale and Its Effects on Groundwater 14C Dating Models

      Muller, A. B.; Mayo, A. L. (American Journal of Science, 1986-01-01)
      In modeling the initial 14C activity of ground waters, the delta-13C of marine limestone is taken conventionally to vary little about 0 per mil PDB. This variation was found to be 6.28 per mil in samples taken over intervals from 10^-2 to 1^5 meters in the Mooney Falls Member of the Redwall Limestone in northern Arizona. Such a variation will cause appreciable variability in the results of all four initial activity models tested. The variability, due primarily to a numerical instability in the models dependent on this parameter, can introduce significant uncertainty into groundwater "age" calculations.
    • Carbon Isotopes in Atmospheric CO2 of the Krakow Region: A Two-Year Record

      Kuc, Tadeusz (American Journal of Science, 1986-01-01)
      We have been measuring concentration of atmospheric CO2 and its carbon isotope composition in the Kraków region for about two years. Samples are continuously collected at two-week intervals at ca 20m above ground level, close to the center of the industrialized urban area. Sampled atmospheric CO2 is sorbed in a molecular sieve and, after recovery by heating, is converted to benzene. 14C is measured in a liquid scintillation spectrometer, and delta-13C of the CO2 is determined in a mass spectrometer. The annual record shows winter-summer variation of 14C, 13C, and CO2 concentration. A long-term trend for 1983 and 1984 indicates a slight decrease of 14C activity (122.0 in January 1983; -1.2% per year), a permanent decrease of delta-13CPDB (-9.3 per mil in January 1983; -0.3 per mil per year) and an increase of CO2 concentration (344ppm in January 1983; 1.4ppm per year).
    • delta-13C and Diet: Analysis of Norwegian Human Skeletons

      Johansen, Olav Sverre; Gulliksen, Steinar; Nydal, Reidar (American Journal of Science, 1986-01-01)
      The relationship between 13C content of human bone and the marine fraction in the individual diet is well established. In the present investigation human skeletons from inland and coastal areas in Norway were analyzed. Both regional and chronologic differences are revealed, and larger variability than expected at specific sites indicate more complex cultural adaptations than earlier recognized. Extremely high delta-13C values, comparable with those obtained from Eskimo sites, are found for material from Early Stone Age fishing/hunting communities.
    • Isotopic Fractionation of Carbon During CO2 Absorption by Mortar

      Pachiaudi, Christiane; Marechal, Joelle; Van Strydonck, Mark; Dupas, Michel; Dauchot-Dehon, Michele (American Journal of Science, 1986-01-01)
    • The Influence of Contaminating (Fossil) Carbonate and the Variations of delta-13C in Mortar Dating

      Van Strydonck, Mark; Dupas, Michel; Dauchot-Dehon, Michele; Pachiaudi, Christiane; Marechal, Joelle (American Journal of Science, 1986-01-01)
      The influence of the aggregate in mortar dating is examined. Sample activity as well as isotopic fractionation approach the expected values at lower yields of the preparation reaction of the counting gas. Good results are obtained at low fossil carbonate concentration. delta-13C cannot give information about this concentration but preliminary visual and chemical analysis of the mortar makes prediction of sample validity possible.
    • Thin Layer delta-13C and Delta-14C Monitoring of "Lessive" Soil Profiles

      Becker-Heidmann, Peter; Scharpenseel, Hans-Wilhelm (American Journal of Science, 1986-01-01)
      The natural 14C and 13C content of soil organic matter and their dependence on depth for two Alfisols are presented. This soil type which covers a large area of the earth's surface is characterized by clay migration processes ("Lessivé"). The samples were taken as successive horizontal layers of 2cm depth from an area of ca 1 m2 size as deep as the C content allows 14C analysis. The minima of the D14C distribution decrease with depth, while the maxima increase in the upper, leached horizon (A1) due to bomb 14C and decrease in the lower, clay illuviated (Bt). delta-13C indicates proceeding decomposition in Al and protection of carbon, probably due to the formation of clay humus complexes in Bt. delta-13C values were also used for age correction of the 14C data due to isotopic fractionation. The D14C and delta-3C depth distributions are characterized by sharp peaks at the boundaries of the horizons, probably caused by the influence of textural changes on the transport of C with percolating water.
    • Trends of 13C/12C Ratios in Pinyon Tree Rings of the American Southwest and the Global Carbon Cycle

      Leavitt, S. W.; Long, Austin (American Journal of Science, 1986-01-01)
      An accurate atmospheric 13C/12C chronology can provide important constraints to models of the global carbon cycle. Trees accumulate carbon from atmospheric CO2 into growth rings and offer potential for 13C/12C reconstructions, but results have not been reproducible. This paper presents 5 degree C curves from 5 sites, representing 20 pinyon (Pinus edulis) trees, where cores of 4 trees from each site have been pooled into a composite sample. Isotopic analysis of cellulose in 5-yr ring groups produces curves with a general trend of decreasing 5 degree C after 1800, but with pronounced short-term fluctuations superimposed upon the trend. Evidence indicates the fluctuations are strongly related to moisture availability (drought). A mean curve of the 5 delta-13C chronologies from which the fossil-fuel component is subtracted suggests a substantial biospheric CO2 contribution to the atmosphere since 1800.