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dc.contributor.authorGlavin, Daniel P.
dc.contributor.authorElsila, Jamie E.
dc.contributor.authorMcLain, Hannah L.
dc.contributor.authorAponte, José C.
dc.contributor.authorParker, Eric T.
dc.contributor.authorDworkin, Jason P.
dc.contributor.authorHill, Dolores H.
dc.contributor.authorConnolly, Harold C.
dc.contributor.authorLauretta, Dante S.
dc.date.accessioned2020-03-24T17:33:21Z
dc.date.available2020-03-24T17:33:21Z
dc.date.issued2020-02-25
dc.identifier.citationGlavin, D.P., Elsila, J.E., McLain, H.L., Aponte, J.C., Parker, E.T., Dworkin, J.P., Hill, D.H., Connolly, H.C., Jr. and Lauretta, D.S. (2020), Extraterrestrial amino acids and L‐enantiomeric excesses in the CM2 carbonaceous chondrites Aguas Zarcas and Murchison. Meteorit Planet Sci. doi:10.1111/maps.13451en_US
dc.identifier.issn1086-9379
dc.identifier.doi10.1111/maps.13451
dc.identifier.urihttp://hdl.handle.net/10150/638053
dc.description.abstractThe abundances, distributions, enantiomeric ratios, and carbon isotopic compositions of amino acids in two fragments of the Aguas Zarcas CM2 type carbonaceous chondrite fall and a fragment of the CM2 Murchison meteorite were determined via liquid chromatography time-of-flight mass spectrometry and gas chromatography isotope ratio mass spectrometry. A suite of two- to six-carbon aliphatic primary amino acids was identified in the Aguas Zarcas and Murchison meteorites with abundances ranging from similar to 0.1 to 158 nmol/g. The high relative abundances of alpha-amino acids found in these meteorites are consistent with a Strecker-cyanohydrin synthesis on these meteorite parent bodies. Amino acid enantiomeric and carbon isotopic measurements in both fragments of the Aguas Zarcas meteorites indicate that both samples experienced some terrestrial protein amino acid contamination after their fall to Earth. In contrast, similar measurements of alanine in Murchison revealed that this common protein amino acid was both racemic (D approximate to L) and heavily enriched in C-13, indicating no measurable terrestrial alanine contamination of this meteorite. Carbon isotope measurements of two rare non-proteinogenic amino acids in the Aguas Zarcas and Murchison meteorites, alpha-aminoisobutyric acid and D- and L-isovaline, also fall well outside the typical terrestrial range, confirming they are extraterrestrial in origin. The detections of non-terrestrial L-isovaline excesses of similar to 10-15% in both the Aguas Zarcas and Murchison meteorites, and non-terrestrial L-glutamic acid excesses in Murchison of similar to 16-40% are consistent with preferential enrichment of circularly polarized light generated L-amino acid excesses of conglomerate enantiopure crystals during parent body aqueous alteration and provide evidence of an early solar system formation bias toward L-amino acids prior to the origin of life.en_US
dc.description.sponsorshipNASA Astrobiology Instituteen_US
dc.language.isoenen_US
dc.publisherWILEYen_US
dc.rightsPublished 2020. This article is a U.S. Government work and is in the public domain in the USA.en_US
dc.rights.urihttps://creativecommons.org/publicdomain/mark/1.0/en_US
dc.titleExtraterrestrial amino acids and L-enantiomeric excesses in the CM2 carbonaceous chondrites Aguas Zarcas and Murchisonen_US
dc.typeArticleen_US
dc.identifier.eissn1945-5100
dc.contributor.departmentUniv Arizona, Lunar & Planetary Laben_US
dc.identifier.journalMETEORITICS & PLANETARY SCIENCEen_US
dc.description.notePublic domain articleen_US
dc.description.collectioninformationThis item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at repository@u.library.arizona.edu.en_US
dc.eprint.versionFinal published versionen_US
dc.source.journaltitleMeteoritics & Planetary Science
refterms.dateFOA2020-03-24T17:33:21Z


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Published 2020. This article is a U.S. Government work and is in the public domain in the USA.
Except where otherwise noted, this item's license is described as Published 2020. This article is a U.S. Government work and is in the public domain in the USA.