• Carbon and nitrogen in carbonaceous chondrites: Elemental abundances and stable isotopic compositions

      Pearson, V. K.; Sephton, M. A.; Franchi, I. A.; Gibson, J. M.; Gilmour, I. (The Meteoritical Society, 2006-01-01)
      We have undertaken a comprehensive study of carbon and nitrogen elemental abundances and isotopic compositions of bulk carbonaceous chondrites. A strategy of multiple analyses has enabled the investigation of hitherto unconstrained small-scale heterogeneities. No systematic differences are observed between meteorite falls and finds, suggesting that terrestrial processing has a minimal effect on bulk carbon and nitrogen chemistry. The changes in elemental abundance and isotopic composition over the petrologic range may reflect variations in primary accreted materials, but strong evidence exists of the alteration of components during secondary thermal and aqueous processing. These changes are reflected within the CM2 and CO3 groups and follow the published alteration scales for those groups. The nitrogen isotope system appears to be controlled by an organic host, which loses a 15N-rich component with progressive alteration. This study recommends caution, however, over the use of bulk carbon and nitrogen information for classification purposes; variance in relative abundance of different components in carbonaceous chondrites is significant and reflects intrameteorite heterogeneities.
    • Carbon isotopic composition of acetic acid generated by hydrous pyrolysis of macromolecular organic matter from the Murchison meteorite

      Oba, Y.; Naraoka, H. (The Meteoritical Society, 2006-01-01)
      Low molecular weight monocarboxylic acids, including acetic acid, are some of the most abundant organic compounds in carbonaceous chondrites. So far, the 13C- and D-enriched signature of water-extractable carboxylic acids has implied an interstellar contribution to their origin. However, it also has been proposed that monocarboxylic acids could be formed by aqueous reaction on the meteorite parent body. In this study, we conducted hydrous pyrolysis of macromolecular organic matter purified from the Murchison meteorite (CM2) to examine the generation of monocarboxylic acids with their stable carbon isotope measurement. During hydrous pyrolysis of macromolecular organic matter at 270-330 degrees C, monocarboxylic acids with carbon numbers ranging from 2 (C2) to 5 (C5) were detected, acetic acid (CH3COOH; C2) being the most abundant. The concentration of the generated acetic acid increased with increasing reaction temperature; up to 0.48 mmol acetic acid/g macromolecular organic matter at 330 degrees C. This result indicates that the Murchison macromolecule has a potential to generate at least ~0.4 mg acetic acid/g meteorite, which is about four times higher than the amount of water-extractable acetic acid reported from Murchison. The carbon isotopic composition of acetic acid generated by hydrous pyrolysis of macromolecular organic matter is ~-27 ppm (versus PDB), which is much more depleted in 13C than the water-extractable acetic acid reported from Murchison. Intramolecular carbon isotope distribution shows that methyl (CH3-)-C is more enriched in 13C relative to carboxyl (-COOH)-C, indicating a kinetic process for this formation. Although the experimental condition of this study (i.e., 270-330 degrees C for 72 h) may not simulate a reaction condition on parent bodies of carbonaceous chondrite, it may be possible to generate monocarboxylic acids at lower temperatures for a longer period of time.
    • Carbonaceous materials in the acid residue from the Orgueil carbonaceous chondrite meteorite

      Garvie, Laurence A. J.; Buseck, Peter R. (The Meteoritical Society, 2006-01-01)
      Insoluble organic matter (IOM) dominates the HF/HCl residue of the Orgueil (CI) carbonaceous chondrite meteorite. The IOM is composed primarily of two C-rich particle types. The first has a fluffy texture similar to crumpled tissue paper, and the second type occurs as solid or hollow nanospheres. High-resolution transmission electron microscope (HRTEM) images of the fluffy material show it is poorly ordered, with small, irregularly shaped regions having fringes with 0.34-0.38 nm spacings and locally 0.21 nm cross-fringes. Nanodiamonds occur in the fluffy material. The rounded C-rich particles are common in the residue and their HRTEM images show neither fringes nor nanodiamonds. Both types of carbonaceous materials have a high aromatic component, as revealed by electron energy-loss spectroscopy (EELS), with up to 10 at% substitution by S, N, and O. The average compositions of the fluffy material and nanospheres are C100S1.9N3.7O4.9 and C100S2.4N5.0O3.9, respectively. The structural and chemical heterogeneity of the carbonaceous materials may represent material from multiple sources.
    • Chemical analyses of meteorites at the Smithsonian Institution: An update

      Jarosewich, Eugene (The Meteoritical Society, 2006-01-01)
      Thirteen new meteorites and three meteorite inclusions have been analyzed. Their results have been incorporated into earlier published data for a comprehensive reference to all analyzed meteorites at the Smithsonian Institution. The six tables facilitate a convenient overlook of meteorite data. Table 1 presents an alphabetical list of analyzed meteorites, Table 2 chemical analyses of stony meteorites, Table 3 chemical analyses of iron meteorites, Table 4 elemental composition of stony meteorites, Table 5 average composition of carbonaceous chondrites and achondrites (falls and finds), and Table 6 presents average composition of H, L, LL, and Antarctic chondrites (falls and finds). The tables are available online at the journal's Web site http://meteoritics.org
    • Chesapeake Bay impact structure: Morphology, crater fill, and relevance for impact structures on Mars

      Horton, J. Wright; Ormö, Jens; Powars, David S.; Gohn, Gregory S. (The Meteoritical Society, 2006-01-01)
      The late Eocene Chesapeake Bay impact structure (CBIS) on the Atlantic margin of Virginia is one of the largest and best-preserved "wet-target" craters on Earth. It provides an accessible analog for studying impact processes in layered and wet targets on volatile-rich planets. The CBIS formed in a layered target of water, weak clastic sediments, and hard crystalline rock. The buried structure consists of a deep, filled central crater, 38 km in width, surrounded by a shallower brim known as the annular trough. The annular trough formed partly by collapse of weak sediments, which expanded the structure to ~85 km in diameter. Such extensive collapse, in addition to excavation processes, can explain the "inverted sombrero" morphology observed at some craters in layered targets.The distribution of crater-fill materials in the CBIS is related to the morphology. Suevitic breccia, including pre-resurge fallback deposits, is found in the central crater. Impact-modified sediments, formed by fluidization and collapse of water-saturated sand and silt-clay, occur in the annular trough. Allogenic sediment-clast breccia, interpreted as ocean-resurge deposits, overlies the other impactites and covers the entire crater beneath a blanket of postimpact sediments.The formation of chaotic terrains on Mars is attributed to collapse due to the release of volatiles from thick layered deposits. Some flat-floored rimless depressions with chaotic infill in these terrains are impact craters that expanded by collapse farther than expected for similar-sized complex craters in solid targets. Studies of crater materials in the CBIS provide insights into processes of crater expansion on Mars and their links to volatiles.
    • Chondrule collisions in shock waves

      Ciesla, F. J. (The Meteoritical Society, 2006-01-01)
      Detailed numerical models have shown that solar nebula shock waves would be able to thermally process chondrules in a way that is consistent with experimental constraints. However, it has recently been argued that the high relative velocities that would be generated between chondrules of different sizes immediately behind the shock front would lead to energetic collisions that would destroy the chondrules as they were processed rather than preserving them for incorporation into meteorite parent bodies. Here the outcome of these collisions is quantitatively explored using a simple analytic expression for the viscous dissipation of collisional energy in a liquid layer. It is shown that molten chondrules can survive collisions at velocities as high as a few hundred meters per second. It is also shown that the thermal evolution of chondrules in a given shock wave varies with chondrule size, which may allow chondrules of different textures to form in a given shock wave. While experiments are needed to further constrain the parameters used in this work, these calculations show that the expected outcomes from collisions behind shock waves are consistent with what is observed in meteorites.
    • Chronostratigraphy, composition, and origin of Ni-rich spinel from the Late Eocene Fuente Caldera section in Spain: One impact or more?

      Robin, E.; Molina, E. (The Meteoritical Society, 2006-01-01)
      Here we report on the stratigraphic distribution and chemical composition of Ni-rich spinel, a specific mineral tracer of meteorite impacts, in the Fuente Caldera section in Spain. A major peak in spinel abundance is observed in a biostratigraphic interval defined by the last occurrence of the planktic foraminifera Porticulasphaera semiinvoluta and the first occurrence of the planktic foraminifera Turborotalia cunialensis. Two other peaks of lower abundances are observed higher up in the same biostratigraphic interval, but geochemical considerations suggest that they likely originate from redeposition by turbiditic currents. Biostratigraphic correlations with the global stratotype section and point for the Eocene/Oligocene boundary of Massignano in Italy give an age of 35.4 +/- 0.2 Ma (1-sigma) for the major peak. This age is indistinguishable from the age of the impact horizon at Massignano (35.5 +/- 0.2 Ma) and within the age uncertainties for the Popigai (35.7 +/- 0.2 Ma) and Chesapeake Bay (35.5 +/- 0.5 Ma) craters. The Fuente Caldera spinel, as the Massignano spinel, is assumed to be a relic mineral of microkrystites, which are believed to derive from a unique source related to the Popigai impact crater. The morphologies and Cr compositions of the Fuente Caldera and Massignano spinel crystals are markedly different, however: the Fuente Caldera spinel occurs mostly as octahedral and skeletal crystals with 85% of the grains belonging to the Cr-rich magnetite series and 15% to the Fe-rich chromite series, whereas the Massignano spinel occurs mostly as dendritic crystals with 90% of the grains belonging to the Cr-poor magnetite series. It is unlikely that these differences are the result of post-depositional alteration processes because the compositions of the crystals, as well as their morphologies, are in general very similar to those reported for primary spinel crystals, i.e., spinel crystals present in meteorite fusion crust or synthetized from meteoritic material. In addition, spinel crystals have quite homogeneous compositions except for a few grains (<10%) showing Cr zonations, but these are assigned to primary crystallization processes. One possible explanation that is consistent with a single impact event producing spatial variations in spinel compositions and morphologies is that microkrystites are locally generated by the ablation in the atmosphere of impact debris. An alternative explanation is that Fuente Caldera and Massignano microkrystites derive from two closely spaced impact events, which however requires another, so-far unknown source crater for microkrystites.
    • Conditions in the protoplanetary disk as seen by the type B CAIs

      Richter, Frank M.; Mendybaev, Ruslan A.; Davis, Andrew M. (The Meteoritical Society, 2006-01-01)
      Type B coarse-grained calcium-aluminum-rich inclusions (CAIs) are the oldest known materials to have formed in the solar system and are a unique source of information regarding conditions and processes in the protoplanetary disk around the young sun. Recent experimental results on the crystallization and evaporation of type B-like silicate melts allow us to place the following constraints on the conditions in the protoplanetary disk during the formation of type B CAIs. 1) Once type B CAIs precursors have been condensed from a solar composition gas, they were reheated at 1250-1450 degrees C, as is indicated by their igneous texture. 2) The melilite mantles characteristic of type B1 CAIs could be formed by crystallization of magnesium- and silicon-depleted melt in the outer part of the partially molten droplets. Such depletion can arise when evaporation is fast compared to chemical diffusion in the melt. This requires the pressure of the surrounding solar composition gas to be at least 10^(-4) bars during the initial crystallization of melilite mantle. Type B2 CAIs with uniform distribution of melilite are expected to form at pressures less than 10^(-5) bars. 3) Evaporation calculations are used to place bounds on the thermal history of the type B CAIs. Observed compositional zoning in melilite suggests that the temperatures in the protoplanetary disk where the type B CAIs resided after crystallization could not have exceeded ~1000 degrees C for more than a few tens of thousands of years. A recent calculation of the physical conditions associated with nebular shocks produced transient temperatures and gas pressures very much like what we find is required to melt reasonable CAI precursors and evaporate these sufficiently quickly to make a type B1 CAI.
    • Confirmation of a meteoritic component in impact-melt rocks of the Chesapeake Bay impact structure, Virginia, USA—Evidence from osmium isotopic and PGE systematics

      Lee, Seung Ryeol; Horton, J. Wright; Walker, Richard J. (The Meteoritical Society, 2006-01-01)
      The osmium isotope ratios and platinum-group element (PGE) concentrations of impact-melt rocks in the Chesapeake Bay impact structure were determined. The impact-melt rocks come from the cored part of a lower-crater section of suevitic crystalline-clast breccia in an 823 m scientific test hole over the central uplift at Cape Charles, Virginia. The 187Os/188Os ratios of impact-melt rocks range from 0.151 to 0.518. The rhenium and platinum-group element (PGE) concentrations of these rocks are 30-270x higher than concentrations in basement gneiss, and together with the osmium isotopes indicate a substantial meteoritic component in some impact-melt rocks. Because the PGE abundances in the impact-melt rocks are dominated by the target materials, interelemental ratios of the impact-melt rocks are highly variable and nonchondritic. The chemical nature of the projectile for the Chesapeake Bay impact structure cannot be constrained at this time. Model mixing calculations between chondritic and crustal components suggest that most impact-melt rocks include a bulk meteoritic component of 0.01-0.1% by mass. Several impact-melt rocks with lowest initial 187Os/188Os ratios and the highest osmium concentrations could have been produced by additions of 0.1%-0.2% of a meteoritic component. In these samples, as much as 70% of the total Os may be of meteoritic origin. At the calculated proportions of a meteoritic component (0.01-0.1% by mass), no mixtures of the investigated target rocks and sediments can reproduce the observed PGE abundances of the impact-melt rocks, suggesting that other PGE enrichment processes operated along with the meteoritic contamination. Possible explanations are 1) participation of unsampled target materials with high PGE abundances in the impact-melt rocks, and 2) variable fractionations of PGE during syn- to post-impact events.
    • Cosmic-ray exposure age and heliocentric distance of the parent bodies of enstatite chondrites ALH 85119 and MAC 88136

      Nakashima, D.; Nakamura, T.; Okazaki, R. (The Meteoritical Society, 2006-01-01)
      We measured concentrations and isotopic ratios of noble gases in enstatite (E) chondrites Allan Hills (ALH) 85119 and MacAlpine Hills (MAC) 88136. These two meteorites contain solar and cosmogenic noble gases. Based on the solar and cosmogenic noble gas compositions, we calculated heliocentric distances, parent body exposure ages, and space exposure ages of the two meteorites. The parent body exposure ages are longer than 6.7 Ma for ALH 85119 and longer than 8.7 Ma for MAC 88136. The space exposure ages are shorter than 2.2 Ma for ALH 85119 and shorter than 3.9 Ma for MAC 88136. The estimated heliocentric distances are more than 1.1 AU for ALH 85119 and 1.3 AU for MAC 88136. Derived heliocentric distances indicate the locations of parent bodies in the past when constituents of the meteorites were exposed to the Sun. From the mineralogy and chemistry of E chondrites, it is believed that E chondrites formed in regions within 1.4 AU from the Sun. The heliocentric distances of the two E chondrite parent bodies are not different from the formation regions of E chondrites. This may imply that heliocentric distances of E chondrites have been relatively constant from their formation stage to the stage of exposure to the solar wind.
    • Cratering and modification of wet-target craters: Projectile impact experiments and field observations of the Lockne marine-target crater (Sweden)

      Ormö, Jens; Lindström, Maurits; Lepinette, Alain; Martinez-Frias, Jess; Diaz-Martinez, Enrique (The Meteoritical Society, 2006-01-01)
      Marine impacts are one category of crater formation in volatile targets. At target water depths exceeding the diameter of the impactor, the zones of vaporization, melting, and excavation of the standard land-target cratering model develop partially or entirely in the water column. The part of the crater that has a potential of being preserved (seafloor crater) may to a great extent be formed by material emplacement and excavation processes that are very different from land-target craters. These processes include a high-energy, water-jet-driven excavation flow. At greater water depths, the difference in strength of the target layers causes a concentric crater to evolve. The crater consists of a wide water cavity with a shallow excavation flow along the seabed surrounding a nested, deeper crater in the basement. The modification of the crater is likewise influenced by the water through its forceful resurge to fill the cavity in the water mass and the seafloor. The resurge flow is strongly erosive and incorporates both ejecta and rip-up material from the seabed surrounding the excavated crater. A combination of field observations and impact experiments has helped us analyze the processes affecting the zone between the basement crater and the maximum extent of the water cavity. The resurge erosion is facilitated by fragmentation of the upper parts of the solid target caused by a) spallation and b) vibrations from the shallow excavation flow and, subsequently, c) the vertical collapse of the water cavity rim wall. In addition, poorly consolidated and saturated sediments may collapse extensively, possibly aided by a violent expansion of the pore water volume when it turns into a spray during passage of the rarefaction wave. This process may also occur at impacts into water-saturated targets without an upper layer of seawater present. Our results have implications for impacts on both Earth and Mars, and possibly anywhere in the solar system where volatiles exist/have existed in the upper part of the target.
    • Density, magnetic susceptibility, and the characterization of ordinary chondrite falls and showers

      Consolmagno, G. J.; Macke, R. J.; Rochette, P.; Britt, D. T.; Gattacceca, J. (The Meteoritical Society, 2006-01-01)
      Bulk and grain densities of 132 ordinary chondrites from the Vatican Observatory collection were measured and compared with their magnetic susceptibility (for the most part using previously measured values; ten new susceptibility measures were taken for this study). Grain density and magnetic susceptibility combined provide a reliable method of classifying un weathered ordinary chondrites. Unlike traditional chemical tests, this method is fast, nondestructive, and characterizes the whole rock, making it especially appropriate for surveying large collections. The system is less viable for finds; extensive weathering of metallic iron in an H chondrite can cause it to plot among L chondrites, while heavily weathered L chondrites plot among the LL group. This system has revealed outlier stones that may be misclassified meteorites or mislabeled samples; in every case where the magnetic susceptibility of a meteorite does not fit its putative classification, the grain density is also found to be in disagreement in a manner consistent with either severe weathering or misidentification. An analysis of stones from five showers shows that, excluding outliers, these samples tend to cluster tightly within their appropriate groups in a plot of grain versus magnetic susceptibility.
    • Desert Meteorites Workshop: Abstracts

      The Meteoritical Society, 2006-01-01
    • Determination of the Fe oxidation state of the Chassigny kaersutite: A microXANES spectroscopic study

      Monkawa, Akira; Mikouchi, Takashi; Koizumi, Eisuke; Sugiyama, Kazumasa; Miyamoto, Masamichi (The Meteoritical Society, 2006-01-01)
      In order to elucidate the formation of low-H kaersutites in Martian meteorites, the Fe3+/Sigma-Fe ratio of Chassigny kaersutites in magmatic inclusions was directly determined by the synchrotron microXANES analysis. XANES analysis for standard kaersutites with known Fe3+/Sigma-Fe ratios shows a linear relationship between centroid energy positions of XANES pre-edge spectra and the Fe3+/Sigma-Fe ratio. Based on the linear relationship, the Fe3+/Sigma-Fe ratio of Chassigny kaersutites is estimated to be about 0.05. The low Fe3+/Sigma-Fe ratio clearly suggests that low-H kaersutites in Chassigny are not likely to be formed by the oxidation-dehydrogenation reactions. The low-H content of the Chassigny kaersutites is mainly due to the presence of a Ti oxy-component.
    • Differentiation and evolution of the IVA meteorite parent body: Clues from pyroxene geochemistry in the Steinbach stony-iron meteorite

      Ruzicka, A.; Hutson, M. (The Meteoritical Society, 2006-01-01)
      We analyzed the Steinbach IVA stony-iron meteorite using scanning electron microscopy (SEM), electron microprobe analysis (EMPA), laser ablation inductively-coupled-plasma mass spectroscopy (LA-ICP-MS), and modeling techniques. Different and sometimes adjacent low-Ca pyroxene grains have distinct compositions and evidently crystallized at different stages in a chemically evolving system prior to the solidification of metal and troilite. Early crystallizing pyroxene shows evidence for disequilibrium and formation under conditions of rapid cooling, producing clinobronzite and type 1 pyroxene rich in troilite and other inclusions. Subsequently, type 2 pyroxene crystallized over an extensive fractionation interval. Steinbach probably formed as a cumulate produced by extensive crystal fractionation (~60-70% fractional crystallization) from a high-temperature (~1450-1490 degrees C) silicate-metallic magma. The inferred composition of the precursor magma is best modeled as having formed by greater than or equal to 30-50% silicate partial melting of a chondritic protolith. If this protolith was similar to an LL chondrite (as implied by O-isotopic data), then olivine must have separated from the partial melt, and a substantial amount (~53-56%) of FeO must have been reduced in the silicate magma. A model of simultaneous endogenic heating and collisional disruption appears best able to explain the data for Steinbach and other IVA meteorites. Impact disruption occurred while the parent body was substantially molten, causing liquids to separate from solids and oxygen-bearing gas to vent to space, leading to a molten metal-rich body that was smaller than the original parent body and that solidified from the outside in. This model can simultaneously explain the characteristics of both stony-iron and iron IVA meteorites, including the apparent correlation between metal composition and metallographic cooling rate observed for metal.
    • Effect of volatiles and target lithology on the generation and emplacement of impact crater fill and ejecta deposits on Mars

      Osinski, Gordon R. (The Meteoritical Society, 2006-01-01)
      Impact cratering is an important geological process on Mars and the nature of Martian impact craters may provide important information as to the volatile content of the Martian crust. Terrestrial impact structures currently provide the only ground-truth data as to the role of volatiles and an atmosphere on the impact-cratering process. Recent advancements, based on studies of several well-preserved terrestrial craters, have been made regarding the role and effect of volatiles on the impact-cratering process. Combined field and laboratory studies reveal that impact melting is much more common in volatile-rich targets than previously thought, so impact-melt rocks, melt-bearing breccias, and glasses should be common on Mars. Consideration of the terrestrial impact-cratering record suggests that it is the presence or absence of subsurface volatiles and not the presence of an atmosphere that largely controls ejecta emplacement on Mars. Furthermore, recent studies at the Haughton and Ries impact structures reveal that there are two discrete episodes of ejecta deposition during the formation of complex impact craters that provide a mechanism for generating multiple layers of ejecta. It is apparent that the relative abundance of volatiles in the near-surface region outside a transient cavity and in the target rocks within the transient cavity play a key role in controlling the amount of fluidization of Martian ejecta deposits. This study shows the value of using terrestrial analogues, in addition to observational data from robotic orbiters and landers, laboratory experiments, and numerical modeling to explore the Martian impact-cratering record.
    • Effects of experimental aqueous alteration on the abundances of argon-rich noble gases in the Ningqiang carbonaceous chondrite

      Yamamoto, Yukio; Okazaki, Ryuji; Nakamura, Tomoki (The Meteoritical Society, 2006-01-01)
      Ar-rich noble gases, the so-called "subsolar" noble gases, are a major component of heavy primordial noble gases in unequilibrated ordinary chondrites and some classes of anhydrous carbonaceous chondrites, whereas they are almost absent in hydrous carbonaceous chondrites that suffered extensive aqueous alteration. To understand the effects of aqueous alteration on the abundance of Ar-rich noble gases, we performed an aqueous alteration experiments on the Ningqiang type 3 carbonaceous chondrite that consists entirely of anhydrous minerals and contains Ar-rich noble gases. Powdered samples and deionized neutral water were kept at 200 degrees C for 10 and 20 days, respectively. Mineralogical analyses show that, during the 10-day alteration, serpentine and hematite formed at the expense of olivine, low-Ca pyroxene, and sulfide. Noble gas analyses show that the 10-day alteration of natural Ningqiang removed 79% of the primordial 36Ar, 68% of the 84Kr, and 60% of the 132Xe, but only 45% of the 4He and 53% of the primordial 20Ne. Calculated elemental ratios of the noble gases removed during the 10-day alteration are in the range of those of Ar-rich noble gases. These results indicate that Ar-rich noble gases are located in materials that are very susceptible to aqueous alteration. In contrast, heavy primordial noble gases remaining in the altered samples are close to Q gas in elemental and isotope compositions. This indicates that phase Q is much more resistant to aqueous alteration than the host phases of Ar-rich noble gases. In the 20-day sample, the mineralogical and noble gas signatures are basically similar to those of the 10-day sample, indicating that the loss of Ar-rich noble gases was completed within the 10-day alteration. Our results suggest that almost all of the Ar-rich noble gases were lost from primitive asteroids during early, low-temperature aqueous alteration.
    • Erratum

      Bhandari, N. (The Meteoritical Society, 2006-01-01)
    • Erratum

      The Meteoritical Society, 2006-01-01
    • Erratum

      The Meteoritical Society, 2006-01-01
      Shock waves-Phenomenology, experimental, and numerial simulationi