Condensation processes in astrophysical environments: The composition and structure of cometary grains

Abstract

We review the results of our recent experimental studies of astrophysical dust analogs. We discuss the condensation of amorphous silicates from mixed metal vapors, including evidence that such condensates form with metastable eutectic compositions. We consider the spectral evolution of amorphous magnesium silicate condensates as a function of time and temperature. Magnesium silicate smokes anneal readily at temperatures of about 1000-1100 K. In contrast we find that iron silicates require much higher temperatures (~1300 K) to bring about similar changes on the same timescale (days to months). We first apply these results to ISO observations of crystalline magnesium silicate grains around high-mass-outflow AGB stars in order to demonstrate their general utility in a rather simple environment. Finally, we apply these experimental results to infrared observations of comets and protostars in order to derive some interesting conclusions regarding large-scale nebular dynamics, the natural production of organic molecules in protostellar nebulae and the use of crystalline magnesium silicates as a relative indicator of a comet's formation age.