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dc.contributor.authorBell, M. S.
dc.date.accessioned2021-02-12T21:41:42Z
dc.date.available2021-02-12T21:41:42Z
dc.date.issued2007-01-01
dc.identifier.citationBell, M. S. (2007). Experimental shock decomposition of siderite and the origin of magnetite in Martian meteorite ALH 84001. Meteoritics & Planetary Science, 42(6), 935-949.
dc.identifier.issn1945-5100
dc.identifier.doi10.1111/j.1945-5100.2007.tb01142.x
dc.identifier.urihttp://hdl.handle.net/10150/656281
dc.description.abstractShock recovery experiments to determine whether magnetite could be produced by the decomposition of iron-carbonate were initiated. Naturally occurring siderite was first characterized by a variety of techniques to be sure that the starting material did not contain detectable magnetite. Samples were shocked in tungsten-alloy holders (W = 90%, Ni = 6%, Cu = 4%) to further ensure that any iron phases in the shock products were contributed by the siderite rather than the sample holder. Each sample was shocked to a specific pressure between 30 to 49 GPa. Transformation of siderite to magnetite as characterized by TEM was found in the 49 GPa shock experiment. Compositions of most magnetites are >50% Fe^+2 in the octahedral site of the inverse spinel structure. Magnetites produced in shock experiments display the same range of sizes (~50-100 nm), compositions (100% magnetite to 80% magnetite-20% magnesioferrite), and morphologies (equant, elongated, euhedral to subhedral) as magnetites synthesized by Golden et al. (2001) and as the magnetites in Martian meteorite Allan Hills (ALH) 84001. Fritz et al. (2005) previously concluded that ALH 84001 experienced ~32 GPa pressure and a resultant thermal pulse of ~100-110 degrees C. However, ALH 84001 contains evidence of local temperature excursions high enough to melt feldspar, pyroxene, and a silica-rich phase. This 49 GPa experiment demonstrates that magnetite can be produced by the shock decomposition of siderite as a result of local heating to >470 degrees C. Therefore, magnetite in the rims of carbonates in Martian meteorite ALH 84001 could be a product of shock devolatilization of siderite as well.
dc.language.isoen
dc.publisherThe Meteoritical Society
dc.relation.urlhttps://meteoritical.org/
dc.rightsCopyright © The Meteoritical Society
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/
dc.subjectmagnetite
dc.subjectAllan Hills 84001 (ALH 84001)
dc.subjectMartian meteorites
dc.subjectnon-biological
dc.subjectshock metamorphism
dc.subjectcarbonates
dc.titleExperimental shock decomposition of siderite and the origin of magnetite in Martian meteorite ALH 84001
dc.typeArticle
dc.typetext
dc.identifier.journalMeteoritics & Planetary Science
dc.description.collectioninformationThe Meteoritics & Planetary Science archives are made available by the Meteoritical Society and the University of Arizona Libraries. Contact lbry-journals@email.arizona.edu for further information.
dc.eprint.versionFinal published version
dc.description.admin-noteMigrated from OJS platform February 2021
dc.source.volume42
dc.source.issue6
dc.source.beginpage935
dc.source.endpage949
refterms.dateFOA2021-02-12T21:41:42Z


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