The origins of sulfate in cenozoic non-marine evaporites in the basin and-range province, southwestern north america

Abstract

Cenozoic evaporites (gypsum and anhydrite) in southwestern North America have wide ranges of δ34 S (−30 to +22‰; most +4 to +10‰) and δ18 OSO4 (+3 to +19‰). New data are presented for five basins in southern Arizona. The evaporites were deposited in playas or perennial saline lakes in closed basins of Oligocene or younger age. Very large accumulations in Picacho, Safford and Tucson Basins have isotope compositions plotting close to a linear δ34 S-δ18 OSO4 relationship corresponding to mixing of two sources of sulfur: (1) sulfate recycled from Permian marine gypsum and (2) sulfate from weathering of Laramide-age igneous rocks that include porphyry copper deposits. In the large evaporites, sulfate with δ34 S > +10‰ is dominantly of Permian or Early Cretaceous marine origin, but has locally evolved to higher values as a result of bacterial sulfate reduction (BSR). Sulfate with δ34 S < −10‰ formed following exposure of sulfides, possibly formed during supergene enrichment of a porphyry copper deposit by BSR, and have values of δ18 OSO4 higher than those of local acid rock drainage because of participation of evaporated water in BSR. Accumulations of 30 to 100 km3 of gypsum in Picacho and Safford Basins are too large to explain as products of contemporaneous erosion of Permian and Laramide source materials, but may represent recycling of Late Cretaceous to Miocene lacustrine sulfate. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.