(4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate
AffiliationDepartment of Chemistry and Biochemistry, University of Arizona
MetadataShow full item record
PublisherInternational Union of Crystallography
CitationRushlow, J., Astashkin, A. V., Albert, D. R., & Rajaseelan, E. (2022). (4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate. IUCrData, 7.
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AbstractThe title compound, [Ir(C8H12)(C6H11N3)(C18H33P)]BF4·CH2Cl2, a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetrafluoridoborate counter-anion, crystallizes with one dichloromethane solvent molecule per formula unit. The IrI atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cycloocta-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a tricyclohexylphosphane ligand. The complex crystallizes in a C-centered monoclinic unit cell and has an unusually high number of eight formula units. © 2022 IUCr. All Rights Reserved.
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Except where otherwise noted, this item's license is described as Copyright © 2022 The Author(s). Published under a CC BY 4.0 licence.