(4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate
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Department of Chemistry and Biochemistry, University of ArizonaIssue Date
2022Metadata
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International Union of CrystallographyCitation
Rushlow, J., Astashkin, A. V., Albert, D. R., & Rajaseelan, E. (2022). (4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate. IUCrData, 7.Journal
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Copyright © 2022 The Author(s). Published under a CC BY 4.0 licence.Collection Information
This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at repository@u.library.arizona.edu.Abstract
The title compound, [Ir(C8H12)(C6H11N3)(C18H33P)]BF4·CH2Cl2, a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetrafluoridoborate counter-anion, crystallizes with one dichloromethane solvent molecule per formula unit. The IrI atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cycloocta-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a tricyclohexylphosphane ligand. The complex crystallizes in a C-centered monoclinic unit cell and has an unusually high number of eight formula units. © 2022 IUCr. All Rights Reserved.Note
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Except where otherwise noted, this item's license is described as Copyright © 2022 The Author(s). Published under a CC BY 4.0 licence.