Azo group-enabled metal- and oxidant-free alkenyl C–H thiolation: Access to stereodefined tetrasubstituted acyclic olefins
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Department of Pharmacology and Toxicology, Department Chemistry and Biochemistry, University of Arizona Cancer Center, BIO5 Institute, University of ArizonaIssue Date
2022Metadata
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KeAi Communications Co.Citation
Gao, H.-J., Miao, Y.-H., Jia, S.-K., Li, N., Xu, L.-P., Wang, W., Wang, M.-C., & Mei, G.-J. (2022). Azo group-enabled metal- and oxidant-free alkenyl C–H thiolation: Access to stereodefined tetrasubstituted acyclic olefins. Green Synthesis and Catalysis.Journal
Green Synthesis and CatalysisRights
Copyright © 2022 Fudan University. Publishing Services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BYNC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).Collection Information
This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at repository@u.library.arizona.edu.Abstract
Metal- and oxidant-free alkenyl C–H thiolation enabled by the azo group had been established for the modular synthesis of tetrasubstituted acyclic olefins. The reaction was performed under mild reaction conditions with a broad substrate scope. The intramolecular 6-membered hydrogen-bonding network accounts for the observed excellent stereo-control. © 2022 Fudan UniversityNote
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Except where otherwise noted, this item's license is described as Copyright © 2022 Fudan University. Publishing Services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BYNC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).